Synthesis and electronic structure of the first cyaphide-alkynyl complexes.
نویسندگان
چکیده
The novel complexes trans-[Ru(dppe)2(C≡CR)(C≡P)] (R = CO2Me, C6H4OMe), the first to incorporate cyaphide as part of a conjugated system, are obtained in facile manner. The electronic structure of these compounds is probed by X-ray, DFT and UV/Vis studies.
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عنوان ژورنال:
- Dalton transactions
دوره 43 24 شماره
صفحات -
تاریخ انتشار 2014